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To make the cookies: Beat together the sugar, butter, salt, baking powder, and espresso powder until fluffy. Beat in the egg and vanilla.
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Whisk together the cocoas and flour, then beat into the egg-butter mixture until well blended.
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Shape the dough into a 1" thick rectangle, wrap it in plastic, and refrigerate for at least 30 minutes.
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While the dough is chilling, make the chocolate topping. Heat 1 cup of the white chocolate in the top of a double boiler (or in a microwave in 30-second increments) until almost fully melted.
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Add an additional 1/2 cup chocolate, stirring until smooth and fully melted; this is a basic way of tempering the chocolate.*
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Place the chocolate molds from your butter cookie set on a baking sheet, and spoon the melted chocolate into the molds. You'll need about a heaping teaspoon of chocolate per mold.
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Once all the molds are filled, gently tap the pan to help remove any bubbles in the chocolate. Allow the chocolate to set until hard.
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Once the chocolate is hard, gently remove each piece from its mold, then refill the molds with chocolate (re-tempering it if necessary). Repeat the process until you've used up all the chocolate.
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To bake the cookies: Preheat the oven to 350°F. Lightly grease two baking sheets, or line with parchment.
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Sprinkle both sides of the chilled dough with extra cocoa, to keep the dough from sticking. Roll it 1/8" thick.
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Cut out rectangles of dough using the cookie stamp from your butter cookie set; it helps to dust the stamp with extra cocoa as well. Place the cookies on the prepared baking sheets.
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Bake the cookies for 8 to 10 minutes, until the edges are firm and you start to smell chocolate.
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Remove the cookies from the oven, and allow them to cool completely.
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To assemble the cookies: Gently spread a thin layer of melted white chocolate on the back of each chocolate piece (to act as glue), then place one on top of each cookie.
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Allow the chocolate pieces to harden in place before serving.
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Yield: about 2 dozen cookies.
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*For more detailed instructions on tempering, see our blog, Flourish.