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Preheat the oven to 400°F. Lightly grease a 9" round cake pan.
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In a medium-sized mixing bowl, whisk together the flour, buttermilk powder (if you're using it), baking powder, salt, sugar, and zest.
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Cut the butter into the dry ingredients, using your fingers, a pastry fork, or a pastry blender, or a mixer with the paddle attachment. Mix until the butter is fairly well combined with the flour; a few lumps remaining are OK.
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Whisk together the egg, vanilla, Fiori and buttermilk or water. Add to the dry ingredients, stirring gently until everything is well moistened and just combined.
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Spread the scone batter in the prepared pan. Spread the marmalade atop the scone batter, gently pushing it down with a fork. Sprinkle with the sparkling sugar.
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Bake the scones in a preheated 400°F oven for 30 minutes, or until the edges are golden brown and a cake tester inserted into the center of one comes out without crumbs clinging to it.
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Remove the pan from the oven, and after 5 minutes, turn the scones out onto a rack, jam side up. While they're still warm, cut the round into wedge-shaped scones.
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Store extra scones for 3 days in a bag on the counter, or freeze for up to 3 months.