

So, my friends, instead of telling stories or sharing jokes this time around, let's talk science. Specifically, let's talk a little bit about the science of simple sugar syrups and their effects on egg whites.
Oh, dear reader, please note that this is just the tip of the iceberg when it comes to egg and sugar science. Consider it just a lick and a promise to get you started.
As you probably know by now, marshmallow is basically egg whites, sugar, and air, plus maybe a little flavoring. Not very complicated ingredients, but definitely a confection that relies heavily on the reactions that happen when sugar is cooked rather than raw. Let's break it down a bit.
The structure of egg-based food and confections is based on the ability of the egg proteins to trap air in little bubbles and keep it there. Take scrambled eggs, for example. It's nothing more than whipping eggs with air and cooking it to solidify the egg proteins before those bubbles burst. Result? Fluffy light scrambled eggs. No whipping in of air? Fried eggs.
Now, if you've ever overcooked scrambled eggs, you'll know how tight and rubbery they get. What's up with that? When your delicate little egg proteins are heated, they begin to tighten up. The hotter they get, the tighter they get. Make them too hot and they become a dense, rubbery mess from which there is no return.
But we can use this tightening to our advantage with the use of a hot sugar syrup. It will sweeten our whipped egg whites AND help them tighten up enough to make sturdy bubbles that will grab together and provide great structure. One thing that adding hot syrup to egg whites will not do is cook them over the recommended safe temperature of 160°F. To be safe when using eggs that are raw or not fully cooked, use pasteurized eggs.
Get ready – here's how we're going to make Homemade Marshmallow Spread.
In a medium-sized heavy saucepan, combine 1/3 cup (74g) water, 3/4 cup (149g) sugar, and 3/4 cup (234g) corn syrup*. Bring to a boil and set a candy thermometer for 240°F.
The temperature will hover in the 220°F range for a long time, and then slowly creep up to the 230°F range. Once it reaches 230°F, it will go fairly quickly for the last 10 degrees.
*Honey can be used instead of the corn syrup; it works just fine.
When the sugar temperature reaches about 225°F, place 3 egg whites and 1/2 teaspoon cream of tartar in the bowl of your mixer. Start off at medium speed until you build up a foamy base, then increase the speed to high until the whites reach soft peaks.
By now the sugar syrup should be at 240°F. With the mixer running, slowly pour a steady stream of syrup along the inside of the bowl. The whites will deflate somewhat as the hot syrup hits, but keep whipping.
Remember, the hot syrup will heat the egg proteins. The proteins will begin to tighten up and a firmer structure will begin to develop. The structure will capture even more air than the whites alone, giving you billowy fluffy goodness.
Take good care as the bowl is quite hot at this stage. I borrowed my husband's handy dandy infrared thermometer to check the temperature. Sorry for the blur, but it's pretty darn hard to hold both this and the camera steady at one time.
Whip the spread for about 8 to 10 minutes, or until the it's thick and white and fluffy. The bowl will cool noticeably as well. When the spread is fairly well cooled, add 1 teaspoon vanilla and whip for another minute.
Pour the barely warm spread into an airtight bowl. Oh yes, it's a bit of a sticky job, but oh so fun!
I don't know about you, but I'm about ready for lunch. Care to split a sandwich?
Please make, rate, and review our recipe for Homemade Marshmallow Spread.
August 23, 2022 at 1:00am
My marshmallow fluff turned out pretty well, but I had some difficulty. Some of the sugar syrup crystalized or solidified--my error was in pouring the stream such that it came in contact with the metal mixing bowl prior to the egg whites. (I rested the lip of the pot with the syrup on the edge of the mixing bowl; the syrup ran down the inner curve of the metal bowl before reaching the egg whites in the bottom of the bowl. That must have cooled off the syrup. I knew there was a problem because my stand mixer started kind of rocking. I poured the remaining syrup more into the middle of the bowl. So I was able to get marshmallow fluff, though I did fish out a large piece--and a few small pieces--of solidified syrup afterwards. Next time, I'd be careful to pour the stream of syrup directly into the beaten egg whites...not allow it to come in contact with the metal bowl first--or at least not to the same extent! The other things I want to mention are that I was kind of surprised the extent to which the sugar/corn syrup darkened as it reached 240 degrees. I used a candy thermometer and removed it promptly when it got to 240. Also I “pasteurized” the eggs the day prior—followed another website’s directions for that (140 degrees for 3 minutes, I think). Finally, I got substantially less yield than some people. The fluff is glossy and thick—but maybe it would have increased in volume with additional beating. Or maybe my “pasteurized” eggs caused less yield—they did form soft peaks nicely, unlike another commentator’s store-bought pasteurized eggs, fwiw.
July 22, 2021 at 4:09pm
How long does the keep? What is the best way to store? Thanks!
July 23, 2021 at 1:15pm
In reply to How long does the keep? … by kgmom (not verified)
Hi there, the marshmallow spread will last about two weeks when stored in an airtight container at cool room temperature (70F). If it's humid or hot, it won't last quite so long.
March 9, 2020 at 5:04pm
Could you layer this with home made ice cream? Say, if you churned the ice cream, and then layered or swirled it with the marshmallow fluff in a container before freezing it? I was trying to find a recipe to use up leftover egg whites, since most ice cream recipes call for about 3 egg yolks, and came across this. What a perfect combination!
March 11, 2020 at 1:36pm
In reply to Could you layer this with… by Kim (not verified)
That's an intriguing question, Kim! With the caveat that we haven't tried it, we think you could make it work if you cooked your marshmallow fluff to a lower temperature to leave it more liquid. Keeping it under 225° or so would give you a better chance of being able to swirl it into your ice cream. It sounds like a delicious experiment!
November 24, 2019 at 9:03am
I'm looking for a substitute for marshmallow cream in making whoopie pies. Would this work? If not, can you make a different suggestion? Thanks.
November 25, 2019 at 4:54pm
In reply to I'm looking for a substitute… by Jeane Bakassoulas (not verified)
We think it would work nicely, Jeane!
September 7, 2014 at 9:28pm
September 8, 2014 at 9:12am
In reply to Older post I know, but how does this freeze? I recently di… by ruthcatrin (not verified)
August 28, 2014 at 12:05pm
Pagination